The question paper will be fully objective type for a total of 150 marks divided into three groups:
Example:
Q. The time independent Schrodinger equation of a system represents the conservation of the
The question may be accompanied by four options P, Q, R, S and the choices may be a combination of these options. The candidate has to choose the right combination as the correct answer.
Example:
Q. The infra-red stretching frequency νco of
(P) Mn(CO)6+ (Q) CO (R) H3B←CO (S) [V(CO)6]- follows the order
Example:
Q. Determine the correctness or otherwise of the following Assertion [a] and the Reason [r]
Assertion: For a fully developed laminar flow in a circular pipe the average velocity is one half of the maximum velocity.
Reason: The velocity for a fully developed laminar flow in a circular pipe varies linearly in the radial direction.
Example:
Q. Match the following and choose the correct combination
Capital |
State |
P. Chennai |
1. Andhra Pradesh |
Q. Bangalore |
2. West Bengal |
R. Mumbai |
3. Rajasthan |
S. Kolkata |
4. Karnataka |
|
5. Tamil Nadu |
|
6. Maharashtra |
(A) |
(B) |
(C) |
(D) |
P - 1 |
P - 5 |
P - 5 |
P - 4 |
Q - 6 |
Q - 4 |
Q - 4 |
Q - 5 |
R - 4 |
R - 3 |
R - 6 |
R - 6 |
S - 5 |
S - 2 |
S - 2 |
S - 2 |
Example:
Common data for Q. 78,79,80: The gas phase reaction, 2P + 4Q → 2R which is first order in P and first order in Q is to be carried out isothermally in a plug flow reactor. The entering volumetric flow rate is 2.5 dm3/min and the feed is equimolar in P and Q. The entering temperature and pressure are 727oC and 10 atm respectively. The specific reaction rate at this temperature is 4 dm3/gmol min and the activation energy is 15,000 cal/gmol.
Q.78. What is the volumetric flow rate in dm3/min when the conversion of P is 25%?
(A) 1.88 (B) 5.40 (C) 7.10 (D) 10.80
Q.79. What is the rate of reaction in gmol/(dm3 min) when the conversion of P is 40%
(A) 1.82 x 103 (B) 4.95 x 10-3 (C) 6.2 x 10-3 (D) 9.73 x 103
Q.80. What is the value of the specific reaction rate constant in dm3/gmol min at 1227oC?
(A) 17.68 (B) 22.32 (C) 49.60 (D) 59.75
Example:
Statement for linked answer Q. 81a & 81b: A reversible Carnot engine operates between the actual heat input temperature of 1000 K and actual heat rejection temperature of 250 K. The ambient temperature is 200 K.
Q.81a The efficiency of this engine will be
A) 5% (B) 20% (C) 25% (D) 75%
Q.81b The above engine is to provide the power output of 100 kW. The heat input required will be
(A) 133.33 kW (B) 400 kW (C) 500 kW (D) 2000 kW
In the above simplistic example, the calculation of heat input in Q.81b requires the value of efficiency calculated in Q.81a as the first step.